Bis[1-(3-cyanobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
نویسندگان
چکیده
In the ionic title complex, (C(13)H(11)N(2))(2)[Ni(C(4)N(2)S(2))(2)], the Ni(II) ion is located on an inversion centre so the asymmetric unit contains one-half [Ni(mnt)(2)](2-) dianion (mnt(2-) is maleonitrile-dithiolate) and one 1-(3-cyano-benz-yl)pyridinium cation ([CNBzPy](+)). The Ni(II) ion in the [Ni(mnt)(2)](2-) anion is coordinated by four S atoms of two mnt(2-) ligands, and exhibits square-planar coordination geometry. In the [CNBzPy](+) cation, the benzene and pyridine rings are twisted with respect to the C/C/N plane incorporating the methyl-ene C atom that links them. The crystal structure is stabilized by Coulombic inter-actions.
منابع مشابه
Bis[1-(ethoxycarbonylmethyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2 S,S′)nickelate(II)
The asymmetric unit of the title ion-pair complex, (C(9)H(12)NO(2))(2)[Ni(C(4)N(2)S(2))(2)], contains two 1-(eth-oxy-carbonyl-meth-yl)pyridinium cations and one bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dianion, which exhibits a slightly distorted square-planar coordination geometry. In the crystal, the cations are linked by strong C-H⋯O hydrogen bonds into C(6) chains along [100]. ...
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The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Ni(C(4)N(2)S(2))(2)], contains one half of an [Ni(mnt)(2)](2-) anion (mnt is maleonitrile-dithiol-ate or 1,2-dicyano-ethene-1,2-dithiol-ate) and one 1-amino-4-methyl-pyridinium cation. The Ni(II) atom is located on an inversion centre. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules.
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متن کاملBis(3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane) bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza-tricyclo-[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2-) (mnt(2-) is maleonitrile-dithiol-ate or 1,2-dicyano-ethene-1,2-dithiol-ate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2-) ligands in a squa...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010